NMR water self-diffusion and relaxation studies on sodium polyacrylate solutions and gels in physiologic ionic solutions
Water self‐diffusion coefficients and longitudinal relaxation rates in sodium polyacrylate solutions and gels were measured by NMR, as a function of polymer content and structure in a physiological concentration range of monovalent and divalent cations, Ca2+ and Na+. Several physical models describing the self‐diffusion of the solvent were applied and compared. A free‐volume model was found …